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À̸§ °ü¸®ÀÚ waterindustry@hanmail.net ÀÛ¼ºÀÏ 2015.12.04 Á¶È¸¼ö 662
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È÷·Î½Ã¸¶ ´ëÇÐ(Hiroshima University)ÀÇ ¿¬±¸ÁøÀº ÇؼöÀÇ Å»¿°(÷­ç¤)À» Çâ»ó½Ãų ¼ö ÀÖ´Â »õ·Î¿î ±â¼úÀ» °³¹ßÇß´Ù. ÀÌ ¿¬±¸°á°ú´Â ÀϺΠ±¹°¡¿¡¼­ ¹ß»ýÇÏ´Â ½Å¼±ÇÑ ¹°¿¡ ´ëÇÑ Áõ°¡ÇÏ´Â ¼ö¿ä¸¦ ÃæÁ·ÇÒ ¼ö ÀÖÀ» °ÍÀÌ´Ù.

¡°½Å¼±ÇÑ ¹°¿¡ ´ëÇÑ ±Û·Î¹ú ºÎÁ·Àº À̹ø ¼¼±â¿¡¼­ Àηù°¡ Á÷¸éÇÏ°í ÀÖ´Â Å« ¾î·Á¿ò ÁßÀÇ Çϳª¡±¶ó°í ÀÌ ¿¬±¸¸¦ À̲ø¾ú´ø Toshinori Tsuru ±³¼ö°¡ ¸»Çß´Ù.

Tsuru ±³¼ö¿Í ±×ÀÇ ¿¬±¸ÁøÀº üÀÇ ¿ªÇÒÀ» ÇÏ´Â »õ·Î¿î Á¾·ùÀÇ ¸Å¿ì ¾ãÀº ¸âºê·¹ÀÎÀ» µðÀÚÀÎÇß°í, ÀÌ ¸âºê·¹ÀÎÀº ¿ª»ïÅõ(reverse osmosis)¶ó°í ¾Ë·ÁÁø ±â¼ú·Î Çؼö¿¡¼­ ¼Ò±ÝÀ» ºÐ¸®Çؼ­ ½Å¼±ÇÑ ¹°À» »ý»êÇÒ ¼ö ÀÖ¾ú´Ù. ÀÌ ¸âºê·¹ÀÎÀº ½Ç¸®ÄÜÀ¸·Î ºÎºÐÀûÀ¸·Î ¸¸µé¾îÁ³°í, ´ã¼ö Ç÷£Æ® ¼³ºñ ¼ÓÀÇ °¡È¤ÇÑ Á¶°ÇÀ» °ßµô ¼ö Àֱ⠶§¹®¿¡ ±âÁ¸ÀÇ ¸î °¡Áö ¹®Á¦µéÀ» ±Øº¹ÇÒ ¼ö ÀÖ¾ú´Ù. ÀÌ ¿¬±¸´Â Journal of Membrane Science¿¡ °ÔÀçµÇ¾ú´Ù.

ÀÌ »õ·Î¿î ÇÏÀ̺긮µå ¸âºê·¹ÀÎÀº À¯¿¬ÇÑ Æú¸®¸Ó ³ª³ë¿©°ú ¸âºê·¹ÀÎ À§¿¡ ÁõÂøµÈ ¸Å¿ì ¾ã°í °áÇÔÀÌ ¾ø´Â À¯±â½Ç¸®Ä« ºÐ¸® ÃþÀ¸·Î ±¸¼ºµÇ¾ú´Ù. ÀÌ ÇÏÀ̺긮µå ¸âºê·¹ÀÎÀº °£´ÜÇÑ Á¹-°Ö(sol-gel), ½ºÇÉ ÄÚÆÃ, Àú¿Â, ¿­Ã³¸® ÇÁ·Î¼¼½º¿¡ ÀÇÇؼ­ ¸¸µé¾îÁ³´Ù. ÀÌ°ÍÀº 2000ppmÀÇ NaCl ¿ë¾×¿¡ ¿ª»ïÅõ Å»¿°À» Àû¿ëÇÑ ÃÖÃÊÀÇ ¿¹ÀÌ´Ù. ¸âºê·¹ÀÎ Á¦Á¶¸¦ À§ÇÑ ÃÖÀûÀÇ ¿­Ã³¸® ¿Âµµ°¡ Á¶»çµÇ¾ú´Ù. ÀÌ·¯ÇÑ ÇÏÀ̺긮µå ¸âºê·¹ÀÎÀº ¿­»ïÅõ ÇÁ·Î¼¼½º¿¡¼­ ¿ì¼öÇÑ ¾ÈÁ¤¼º°ú ÀçÇö¼ºÀ» °¡Áö°í ÀÖ°í, ±âÁ¸ÀÇ Ã³¸® ±â¼ú(96%)°ú °æÀïÇÒ ¼ö ÀÖ´Â ¿° Á¦°ÅÀ²À» °¡Áö°í ÀÖÀ¸¸ç, ¾ÈÁ¤ÀûÀ̸鼭 ³ôÀº ¼öÁØÀÇ Åõ¼ö¼º(´ë·« 1.2¡¿10−12 m3 m−2 s−1 Pa−1)À» °¡Á³´Ù. ¶ÇÇÑ ÀÌ·± ÇÏÀ̺긮µå ¸âºê·¹ÀÎÀº 25¡É ~ 60¡ÉÀÇ ÀÛµ¿ ¿Âµµ¿¡¼­ ¿ì¼öÇÑ ¼ö¿­ ¾ÈÁ¤¼º°ú 160½Ã°£ ÀÌ»ó µ¿¾È Áö¼ÓµÇ´Â ¾ÈÁ¤ÀûÀÎ ¿ª»ïÅõ ¼º´ÉÀ» °¡Á³´Ù.

ºÐ¸® ¸âºê·¹ÀÎÀÇ ÇÑ °¡Áö ¹®Á¦Á¡Àº ¡°»ý¹° ºÎÂø(biofouling)¡±ÀÌ´Ù. »ý¹° ºÎÂøÀº »ý¹°¸·(biofilm)ÀÌ ¸âºê·¹ÀΠǥ¸é À§¿¡ Çü¼ºµÇ´Â °ÍÀ» ÀǹÌÇÑ´Ù. ÀÌ°ÍÀº ¸âºê·¹ÀÎÀ» Åë°úÇÏ´Â ¹°ÀÇ ¾çÀ» ´À¸®°Ô ÇÑ´Ù. Â÷¾Æ¿°¼Ò»ê³ªÆ®·ý(Sodium hypochlorite)Àº ÀÌ·¯ÇÑ »ý¹°¸·À» Á¦°ÅÇϴµ¥ ÀϹÝÀûÀ¸·Î »ç¿ëµÈ´Ù. ±×·¯³ª ÀÌ·± ¿°¼Ò´Â ¸âºê·¹Àο¡ ¼Õ»óÀ» ÁØ´Ù.

ÀÌ ¿¬±¸´Â CREST(Core Research for Evolutional Science and Technology)·ÎºÎÅÍ ÀÚ±ÝÀ» Áö¿ø¹Þ¾Ò´Ù. »õ·Î¿î ¸âºê·¹ÀÎÀº °­Çϱ⠶§¹®¿¡ ¿°¼Ò¿¡ ÀúÇ×ÇÒ ¼ö ÀÖ´Ù. ¶ÇÇÑ ±×µéÀº ³»¿­¼ºÀ» °¡Áö´Âµ¥, ÀÌ°ÍÀº 80¡ÆCÀÇ ¿Âµµ¿¡¼­ Å»¿°À» ÇÒ ¼ö ÀÖ°Ô ÇÑ´Ù.

¡°¿ì¸®´Â ½Ç¸®ÄÜ°è ¹°Áú, źȭ¼ö¼Ò, È­ÇÐ ±â»ó ÁõÂøÀ» »ç¿ëÇؼ­ °­ÇÑ ¸âºê·¹ÀÎÀ» °³¹ßÇß´Ù¡±°í Tsuru ±³¼ö°¡ ¸»Çß´Ù. ¡°¿ì¸®´Â ÀÌ ¿¬±¸·Î ÀÎÇؼ­ ÀϺ»ÀÌ ¸âºê·¹ÀÎ ±â¼ú°ú ¸·-ó¸® ½Ã½ºÅÛÀÇ ¼±µÎ ±¹°¡ Áß Çϳª·Î¼­ÀÇ À§Ä¡¸¦ °è¼ÓÀûÀ¸·Î °¡Áú ¼ö ÀÖÀ» °ÍÀ̶ó°í ±â´ëÇÏ°í ÀÖ´Ù¡±°í ±×´Â ¸»Çß´Ù.

ROBUST ¸âºê·¹ÀÎ ÇÁ·ÎÁ§Æ®ÀÇ ¼Ò°³

ROBUST ¸âºê·¹ÀÎ ÇÁ·ÎÁ§Æ®´Â JST(Japan Science and Technology Agency)¿¡¼­ ÀÚ±ÝÀÌ Áö¿øµÈ À¯¸ÁÇÑ ¿¬±¸ ÇÁ·ÎÁ§Æ® ÁßÀÇ ÇϳªÀÌ´Ù. ÀÌ ÇÁ·ÎÁ§Æ®ÀÇ ¸ñÀûÀº pH ȤÀº °í¿Â°ú ¿°¼Ò¸¦ Æ÷ÇÔÇÏ´Â ¹° ¼Ó¿¡¼­ »ç¿ëµÉ ¼ö ÀÖ´Â ROBUST ¿ª»ïÅõ/³ª³ë¿©°ú ¸âºê·¹ÀÎÀ» °³¹ßÇÏ´Â °ÍÀÌ´Ù. ÀÌ ÇÁ·ÎÁ§Æ®´Â ´Ù¾çÇÑ Á¾·ùÀÇ ¼öÀÚ¿ø¿¡¼­ ROBUST ¸âºê·¹ÀÎÀÇ Àû¿ë °¡´É¼ºÀ» Á¶»çÇÒ ¸ñÀûÀ¸·Î ÁøÇàµÇ°í ÀÖ´Ù. ÀÌ ¿¬±¸°á°ú´Â Journal of Membrane Science¿¡ ¡°Reverse osmosis performance of layered-hybrid membranes consisting of an organosilica separation layer on polymer supports¡±¶ó´Â Á¦¸ñÀ¸·Î °ÔÀçµÇ¾ú´Ù.

±×¸². »õ·Î¿î ÇÏÀ̺긮µå ¸âºê·¹ÀÎÀÇ Àý´Ü¸é SEM À̹ÌÁö.

[Ãâó = KISTI ¹Ì¸®¾È ¡º±Û·Î¹úµ¿Çâºê¸®ÇΡ»/ 2015³â 12¿ù 4ÀÏ]

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Nanomembrane technology improves the removal of salt from seawater

Researchers at Hiroshima University have developed a technology that improves the removal of salt from seawater, a breakthrough that may alleviate the increasing demand for fresh water in some countries.

"A global shortage of fresh water is a long-term challenge that mankind faces in this century," said the director of the ROBUST membrane project, Professor Toshinori Tsuru.

Professor Tsuru and his team have designed a new kind of ultra-thin layered membrane that acts as a sieve and separates salt from seawater to produce fresh water, a technique known as reverse osmosis. The membrane is partly made from silicon and overcomes several challenges of existing designs by tolerating the harsh conditions inside desalination plant equipment. The research has been published in the Journal of Membrane Science ("Reverse osmosis performance of layered-hybrid membranes consisting of an organosilica separation layer on polymer supports").

One practical problem of separation membranes is "biofouling", where biofilms form on the membrane surface. This slows the amount of water that can pass through the membrane. Sodium hypochlorite is commonly used to remove these biofilms; however, the chlorine can also damage the membrane.

Professor Tsuru, who is supported by CREST (Core Research for Evolutional Science and Technology) and is a member of the Center for Research on Environmentally Friendly Smart Materials at Hiroshima University's Institute of Engineering, said that the new membranes are more robust, which makes them resistant to chlorine. They are also heat resistant, meaning they can be used in desalination at a temperature of 80¡ÆC.

"We are developing ROBUST membranes using three materials: silicon-based, hydrocarbon, and chemical vapor deposition. First we have developed silicon-based ROBUST membranes," Professor Tsuru said.

"We expect Japan to continue to be one of the leading countries in membrane technologies and membrane-treatment systems," he said.

About the ROBUST membrane project

The ROBUST membrane project is one of the CREST programs for promising research projects funded by the Japan Science and Technology Agency (JST). The purpose of this project is to develop ROBUST reverse osmosis (RO)/nanofiltration (NF) membranes that can be used in water containing chloride at a wide range of pH and/or at high temperatures. The project aims to examine the applicability of the ROBUST membrane for various types of water resources.
 
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