ORP Based Measurement of Oxidizing Disinfectants in Aqueous Solutions Test methods based on ORP as an alternate method for measuring the presence of oxidizing disinfectants in aqueous solutions.
By Richard James Spahl Quality Engineering Manager, Myron L Company
Oxidizing antimicrobials, such as chlorine, are common disinfectants used to treat water. Test strips, DPD kits and colorimeters are currently the most popular methods for determining the relative disinfecting power of oxidizing antimicrobial agents in these applications. Unfortunately, these testing options often target narrowly specific sets of chemicals and chemical reactions that may have little to do with the actual chemistry of your water or disinfectant method. This article explains how ORP measurement works and why an ORP based test method is a flexible and effective alternative for determining disinfectant power of oxidizing antimicrobial agents in aqueous solutions.
ORP Defined
ORP stands for Oxidation-Reduction Potential. An oxidation-reduction (REDOX) reaction is an electrochemical process during which electrons are passed between different chemicals. The terms oxidizer and oxidation are related but not exactly the same. Substances that acquire electrons are called oxidizers (also oxidants or oxidizing agents) however the process by which an oxidizer gains electrons is referred to as reduction. Conversely, chemicals that lose electrons are called reducers (also called reductants or reducing agents) but the process by which they give up those electrons is referred to as oxidation.
REDOX reactions are usually defined in terms of half-reactions. A reduction half-reaction is one where the oxidizer gains electrons and an oxidation half-reaction is one where the reducer loses electrons.