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À̸§ °ü¸®ÀÚ waterindustry@hanmail.net ÀÛ¼ºÀÏ 2014.07.31 Á¶È¸¼ö 371
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ȯ°æÀûÀÎ ¹°¿¡¼­ ¼öÀºÀ» °ËÁöÇÏ´Â ±Øµµ·Î ¹Î°¨ÇÏ°í ºñ¿ëÀÌ Àú·ÅÇÑ »õ·Î¿î ÈÞ´ëÇü ½Ã½ºÅÛÀÌ, È£ÁÖ ¾Öµé·¹ÀÌµå ´ëÇб³(University of Adelaide) ¿¬±¸Áøµé¿¡ ÀÇÇØ °³¹ßµÇ¾ú´Ù. ¹Ì±¹ È­ÇÐÇùȸ(ACS) [Applied Materials and Interfaces] Àú³Î¿¡ ¹ßÇ¥µÈ ±Û¿¡¼­, ¿¬±¸ÆÀÀº °ü½É´ë»ó ÇöÀå¿¡¼­ ³·Àº ¼öÁØÀÇ ¼öÀºÀ» °ËÁöÇÏ´Â µ¥ Àû´çÇÑ Çõ½ÅÀûÀÎ ±¤ÇÐ ¼¾½Ì½Ã½ºÅÛÀ» ¼±º¸¿´´Ù.

"¼öÀºÀº »ê¾÷È­ÀÇ Ãâ¹ß ¶§ºÎÅÍ ÀÚ¿¬È¯°æ¿¡ ÃàÀûµÇ¾î ¿À°í ÀÖÀ¸¸ç, »ç¶÷ÀÇ °Ç°­°ú ȯ°æ¿¡ ¹ÌÄ¡´Â ¿µÇâ¿¡ ´ëÇØ ¼¼°èÀûÀÎ °ü½ÉÀ» ÁÖ°í ÀÖ´Ù"°í ÀÌ ´ëÇб³ È­ÇаøÇÐ ½ºÄð(School of Chemical Engineering)ÀÇ È£ÁÖ ¿¬±¸À§¿øȸ ¹Ú»ç ÈÄ Æç·Î¿ìÀÌÀÚ ÇÁ·ÎÁ§Æ® Ã¥ÀÓÀÚÀÎ ¾Æº§ »êÅ佺(Abel Santos) ¹Ú»ç´Â ¸»Çß´Ù.

"ÃÖ±Ù¿¡, ÀÌ·¯ÇÑ °ü½ÉÀº ¼¼°èÀûÀÎ ±Ô¸ð¿¡¼­ ¼öÀº ¿À¿°À» °ü¸®ÇÏ°í ¸ð´ÏÅ͸µÇÏ¸ç °¨¼Ò½ÃÅ°´Â ¸ñÀûÀÇ °¢Á¾ ±Û·Î¹ú ȸÀÇÀÇ µµÀÔÀ¸·Î ³ªÅ¸³ª°í ÀÖ´Ù. ¹Ì·® ¼öÁØ¿¡¼­ ¼öÀºÀ» ¸ð´ÏÅ͸µÇÒ ¼ö ÀÖ´Â ÇöÀçÀÇ ½Ã½ºÅÛÀº ÀÖÁö¸¸, °Å´ëÇÑ ±â°è´Â ½±°Ô À̵¿ÇÒ ¼ö ¾ø°í ¸Å¿ì ºñ½Î¸ç »ç¿ëÇϱ⠾î·Æ°í »ó´çÇÑ ÈÆ·ÃÀÌ ÇÊ¿äÇÏ´Ù. ¶ÇÇÑ, ºÐ¼® ÀÌÀü¿¡ È­ÇÐÀû 󸮰¡ ÇÊ¿äÇÏ´Ù. ¿ì¸®°¡ °³¹ßÇÑ ½Ã½ºÅÛÀº ¸Å¿ì ºñ¿ë °æÀï·ÂÀÌ ÀÖ°í ÈÞ´ëÀüÈ­±â Á¤µµÀÇ Å©±âÀÌ¸ç »ç¿ëÇϱⰡ ½±´Ù. ¸Å¿ì ±âº»ÀûÀÎ ±³À°¸¸À¸·Î, ¾Æ¹«³ª °­À̳ª È£¼ö¿¡ °¡¼­ ÇöÀåÀÇ ¼öÀº °ªÀ» Àд °ÍÀÌ °¡´ÉÇÏ´Ù"°í »êÅ佺 ¹Ú»ç´Â µ¡ºÙ¿´´Ù.

ÀÌ ÇÁ·ÎÁ§Æ®´Â ½ºÆäÀÎ ·Îºñ¶ó ºñ¸£Áú¸® ´ëÇб³(Rovira i Virgili University)¿Í È£ÁÖ ¾Öµé·¹ÀÌµå ´ëÇб³ È­ÇаøÇÐ ½ºÄðÀÇ ·Î½Ä ³ª³ë ¿¬±¸±×·ì(Losic Nano Research group) °£ÀÇ Çù·Â ¿¬±¸À̸ç, ½ÇÇè ÀÛ¾÷ÀÇ ´ëºÎºÐÀº ¹Ú»ç°úÁ¤ ÇлýÀÎ ÅͼŠÄí¸Þ¸®¾Æ(Tushar Kumeria)¾¾°¡ ¼öÇàÇß´Ù. ¿¬±¸ÆÀÀº ·ç°ÔÀÌÆ® ÇÊÅÍ(rugate filter)¶ó°í ºÒ¸®´Â Ư¼öÇÑ ±¸Á¶Ã¼¸¦ Á¦ÀÛÇϱâ À§ÇØ ³ª³ë´Ù°ø¼º ¾ç±Ø »êÈ­ ¾Ë·ç¹Ì³ª(nanoporous anodic alumina)¶ó°í ºÒ¸®´Â ³ª³ë´Ù°ø¼º ¹°ÁúÀ» ¿£Áö´Ï¾î¸µÇß´Ù.

ÇÊÅÍÀÇ Ç¥¸éÀº ¼öÀº À̿¿¡ ¼±ÅÃÀûÀ¸·Î Àû¿ëµÇ±â À§ÇØ ¼öÁ¤µÇ¾ú´Ù. ¹°ÀÌ ÇÊÅÍÀÇ ±¸¸ÛÀ» ÅëÇØ Èê·¯°¨¿¡ µû¶ó, ¼öÀº ÀÌ¿ÂÀº Ç¥¸é¿¡ ´Þ¶óºÙ°Ô µÈ´Ù. ¹Ý»ç ºÐ±¤¹ý(reflection spectroscopy)ÀÇ ±¤ÇнýºÅÛÀº Á¸ÀçÇÏ´Â ¼öÀºÀÇ ¾çÀ» ÃøÁ¤ÇÑ´Ù.

ÀÏ·ÃÀÇ ½ÃÇè°á°ú¿¡ ÀÇÇϸé, ÀÌ ¼¾¼­´Â ´Ù¸¥ ±Ý¼Ó À̿°ú ȯ°æ »ùÇÃÀÌ È¥ÇÕµÈ º¹ÀâÇÑ È¥ÇÕ¹° ³»¿¡¼­ 200ppb(parts per billion) ¼öÁØÀÇ ¼öÀºÀ» °ËÁöÇÒ ¼ö ÀÖ´Ù. °è¼ÓµÈ ¿¬±¸°¡ ÀÌ ±¤ÇÐ ½ÅÈ£¸¦ ´õ ³ôÀº ¹Î°¨µµ¸¦ °¡Áöµµ·Ï ÇÒ °ÍÀÌ´Ù.

"ÀÌ ½Ã½ºÅÛÀÌ °¡Áø ºñ¿ë°æÀï·Â°ú ÈÞ´ë¿ë À̿뼺 ±×¸®°í ¼¾½Ì ¼º´ÉÀº ÇöÀçÀÇ ºÐ¼® ±â¼úº¸´Ù ¿ì¼öÇÑ ´ë¾ÈÀÌ µÉ ¼ö ÀÖ´Ù. ÀÌ ±â¼úÀº ÇöÀåÀÇ ¼öÁúÀ» ¸ð´ÏÅ͸µÇϱâ À§ÇÑ ¹Ì·¡ÀÇ ºÐ¼®½Ã½ºÅÛ ±â¹ÝÀ» Á¦°øÇÏ°í, ¼¼°èÀÇ ¸ð´ÏÅ͸µ ÇÁ·Î¼¼½º¸¦ ´õ¿í È¿À²ÀûÀ¸·Î ¸¸µé ¼öµµ ÀÖÀ» °Í"À̶ó°í »êÅ佺(Santos) ¹Ú»ç´Â ¸»Çß´Ù.

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New system to detect mercury in water systems

A new ultra-sensitive, low-cost and portable system for detecting mercury in environmental water has been developed by University of Adelaide researchers.
Published in the journal ACS Applied Materials and Interfaces, the research team outlined its innovative optical sensing system suitable for detecting low levels of mercury at the site of interest.

"Mercury has been accumulating in the natural environment since the start of industrialization and there are worldwide concerns about potential human health and environmental effects," says project leader Dr Abel Santos, Australian Research Council Postdoctoral Fellow with the University's School of Chemical Engineering.

"Recently, these concerns have seen the introduction of a global convention aimed at controlling, monitoring and reducing mercury pollution at a world scale.
"There are current systems capable of monitoring mercury at trace levels, but they are huge machines that can't be easily moved, are very expensive and complicated to use and require comprehensive training. Samples also require chemical treatment before analysis.
"Our system is very cost-competitive, only as big as a mobile phone and easy to use. With very basic training, someone could take it to a river or lake and do a mercury reading on the spot."

The project is a collaboration between the Losic Nano Research group in the School of Chemical Engineering and University Rovira i Virgili in Spain, and most of the experimental work has been carried out by PhD candidate Tushar Kumeria. The team has engineered a nanoporous material called nanoporous anodic alumina to make a special structure called a rugate filter.

The surface of the filter has been modified to make it selective to mercury ions. As water flows through the pores of the filter, the mercury ions become attached to the surface. An optical system -- reflection spectroscopy -- measures the amount of mercury present.

A range of tests have shown the sensor can detect mercury at levels of 200 parts per billion in a complex mixture of other metal ions and environmental samples. Continued work will seek to enhance the optical signals for even higher sensitivity.

"The promising sensing performance of this system along with its cost-competiveness and portability make it an excellent potential alternative to current analytical techniques," says Dr Santos. "This technique could provide the basis for future point-of-analysis systems for monitoring water quality on site and may help implement better monitoring processes around the world."

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